A methodology for spirocyclopentannulation. Stereoselective total synthesis of (±)-tochuinyl acetate and (±)-dihydrotochuinyl acetate

Srikrishna, A. ; Jagadeeswar Reddy, T. ; Praveen Kumar, P. ; Vijaykumar, D. (1996) A methodology for spirocyclopentannulation. Stereoselective total synthesis of (±)-tochuinyl acetate and (±)-dihydrotochuinyl acetate Synlett, 1996 (1). pp. 67-68. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-1996-5318

Abstract

A methodology based on Claisen rearrangement and Wacker oxidation for the spirocyclopentannulation of ketones, and its application to a highly stereoselective first total synthesis of dihydrotochuinyl acetate (8) is described.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Spiro Compounds; Claisen Rearrangement; Wacker Oxidation; Quaternary Carbon Atoms; Tochuinyl Acetates
ID Code:51569
Deposited On:28 Jul 2011 14:29
Last Modified:28 Jul 2011 14:29

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