Synthesis and structure of the [MnIV(biguanide)3]4+ ion: the simplest source for water-stable manganese(IV)

Das, Gopal ; Bharadwaj, Parimal . ; Ghosh, Debjani ; Chaudhuri, Beauty ; Banerjee, Rupendranath (2001) Synthesis and structure of the [MnIV(biguanide)3]4+ ion: the simplest source for water-stable manganese(IV) Chemical Communications (4). pp. 323-324. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B007013K

Abstract

Aqueous oxidation of alkaline biguanide sulfate with KMnO4 followed by crystallisation from 2 M HNO3 yields the mononuclear [Mn(bigH)3]4+ ion, which has been characterised crystallographically and provides an easy route to mononuclear, water-stable manganese(IV).

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