Srikrishna, A. ; Gharpure, Santosh J. (1998) An intramolecular rhodium carbenoid C-H insertion approach to chiral isotwistanes. Synthesis of (−)-neopupukean-4, 10-dione and (−)-neopupukean-10-one Chemical Communications (15). pp. 1589-1590. ISSN 0009-241X
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1998...
Related URL: http://dx.doi.org/10.1039/A804001J
Abstract
The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Michael reaction and a regioselective intramolecular rhodium carbenoid C-H insertion reaction as key steps, is described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 48891 |
| Deposited On: | 19 Jul 2011 08:44 |
| Last Modified: | 19 Jul 2011 08:44 |
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