Acid-catalysed thermal rearrangement of γ,δ-unsaturated ketones

Srikrishna, Adusumilli ; Krishnan, Kathiresan ; Vankateswarlu, Somepalli (1993) Acid-catalysed thermal rearrangement of γ,δ-unsaturated ketones Journal of the Chemical Society, Chemical Communications (2). pp. 143-145. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/content/articlepdf/1993/c3/...

Related URL: http://dx.doi.org/10.1039/C39930000143

Abstract

Thermal activation of γ,δ-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new γ,δ-unsaturated ketones (2, 10 and 14) via an intramolecular ene reaction followed by a retro-ene reaction.

Item Type:Article
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ID Code:48888
Deposited On:19 Jul 2011 08:41
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