Reaction of dialkyl 2-butynoate with aniline and formaldehyde: revision of the structure of the product

Srikrishna, A. ; Sridharan, M. ; Prasad, K. R. (2010) Reaction of dialkyl 2-butynoate with aniline and formaldehyde: revision of the structure of the product Tetrahedron, 66 (21). pp. 3651-3654. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2010.03.084

Abstract

Dimethyl 3-(aryl)-3,6-dihydro-2H-1,3-oxazine-4,5-dicarboxylate structure assigned for the products obtained in the Bronsted acid catalyzed reaction of dimethyl but-2-ynoates with anilines and an excess of formaldehyde in methanol has been revised to methyl 1-(aryl)-3-(methoxymethyl)-4,5-dioxopyrrolidine-3-carboxylate.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Domino Reactions; Dialkyl 2-Butynoates; 1,3-Dioxazines; Tetrahydropyrimidines; 3-oxo-2-Pyrrolidinones; Structure Revision; Multi-component Reaction
ID Code:48805
Deposited On:15 Jul 2011 12:32
Last Modified:15 Jul 2011 12:32

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