Total synthesis of (±)-β-chamigrene and (±)-laurencenone C via Ireland ester Claisen rearrangement and an intramolecular type II carbonyl ene reaction sequence

Srikrishna, A. ; Ramesh Babu, R. (2008) Total synthesis of (±)-β-chamigrene and (±)-laurencenone C via Ireland ester Claisen rearrangement and an intramolecular type II carbonyl ene reaction sequence Tetrahedron, 64 (46). pp. 10501-10506. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2008.08.095

Abstract

A combination of Ireland ester Claisen rearrangement and intramolecular type II carbonyl ene reactions were exploited for the total synthesis of chamigrenes containing a quaternary carbon atom next to the spirocentre in spiro[5.5]undecane.

Item Type:Article
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ID Code:48783
Deposited On:15 Jul 2011 11:52
Last Modified:15 Jul 2011 11:52

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