A simple strategy for spirocyclopentannulation of cyclic ketones. Formal total synthesis of (±)-acorone

Srikrishna, Adusumili ; Praveen Kumar, P. ; Viswajanani, Ranganathan (1996) A simple strategy for spirocyclopentannulation of cyclic ketones. Formal total synthesis of (±)-acorone Tetrahedron Letters, 37 (10). pp. 1683-1686. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-4039(96)00109-8

Abstract

A general and simple methodology for spirocyclopentannulation of cyclic ketones (or 4,4-disubstituted cyclopentenones from acyclic ketones) and its application in the synthesis of the spirodienone 7̲ via a prochiral precursor constituting a formal total synthesis of (±)-acorone (6̲), are described.

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