Photoinitiated oxidation of heterophasic ethylene–propylene copolymers. I. Comparison of oxidation products

Singh, R. P. ; Mani, R. ; Sivaram, S. ; Lacoste, J. ; Vaillant, D. (1993) Photoinitiated oxidation of heterophasic ethylene–propylene copolymers. I. Comparison of oxidation products Journal of Applied Polymer Science, 50 (11). pp. 1871-1881. ISSN 0021-8995

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/app.199...

Related URL: http://dx.doi.org/10.1002/app.1993.070501103

Abstract

Detailed photoproducts from photoirradiation of heterophasic ethylene-propylene copolymers and their fractions have been compared by infrared spectroscopy combined with chemical derivatization. The oxidized films were treated with gaseous NH3, SF4, and NO for the rapid identification and resolution of the various carbonyl species, alcohols, and hydroperoxides. The photoproduct formation depends upon the composition of the sample. The heterogeneities in thin films were also determined by micro FTIR spectroscopy.

Item Type:Article
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