Sarma, D. D. ; Taraphder, A. (1989) Electronic structure of high-Tc cuprates from core-level photoemission spectroscopy Physical Review B: Condensed Matter and Materials Physics, 39 (16). pp. 11570-11574. ISSN 1098-0121
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Official URL: http://prb.aps.org/abstract/PRB/v39/i16/p11570_1
Related URL: http://dx.doi.org/10.1103/PhysRevB.39.11570
Abstract
The core photoemission spectrum of a copper +2 impurity embedded in a square lattice of oxygen -2 has been calculated using an extended Anderson impurity Hamiltonian including a Cu 3d hole-O 2p hole repulsive interaction. Comparison with experimental data shows that the ground state of the system is a mixed-valent insulator in the absence of hole doping, in spite of the Cu 3d level being within the oxygen 2p-derived band. Doping of an extra hole induces a transition to a weakly mixed-valent metallic state with drastic modifications in the calculated core-level spectrum.
Item Type: | Article |
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Source: | Copyright of this article belongs to The American Physical Society. |
ID Code: | 46385 |
Deposited On: | 04 Jul 2011 11:38 |
Last Modified: | 04 Jul 2011 11:38 |
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