Ayyappan, S. ; Cheetham, A. K. ; Natarajan, Srinivasan ; Rao, C. N. R. (1998) A novel monomeric tin(II) phosphate, [N(C2H5NH3)3]3+[Sn(PO4)(HPO4)]3−·4H2O, connected through hydrogen bonding Journal of Solid State Chemistry, 139 (1). pp. 207-210. ISSN 0022-4596
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00224...
Related URL: http://dx.doi.org/10.1006/jssc.1998.7897
Abstract
The tin(II) phosphate, [N(C2H5NH3)3]3+[Sn(PO4)(HPO4)]3−4H2O, contains monomeric Sn2(PO4)2(HPO4)2 units which form a hydrogen-bonded network with the TREN amine (TREN=N(C2H5NH3)3+3); triclinic, space groupP1 (no. 2), a=9.579(1), b=10.507(1), c=10.976(1) Å; α=72.93(1)°, β=78.03(1)°, γ=69.82(1)°, V=984.2(1) Å3, Z=2. The Sn2P2O4 core of this unit is a common structural feature of open-framework tin phosphates and may play a role as a building block for this class of materials.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 40091 |
| Deposited On: | 21 May 2011 08:33 |
| Last Modified: | 28 May 2011 12:20 |
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