Ramakrishna Matte, H. S. S. ; Swain, Sarat K. ; Thirumurugan, A. ; Rao, C. N. R. (2009) Two- and three-dimensional hybrid compounds formed by 1,2-, 1,3- and 1,4-cyclohexanedicarboxylates of zinc Zeitschrift für Anorganische und Allgemeine Chemie, 635 (12). pp. 1840-1847. ISSN 0044-2313
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.20...
Related URL: http://dx.doi.org/10.1002/zaac.200900096
Abstract
By employing the hydrothermal method, five zinc cyclohexanedicarboxylates (CHDCs) with the compositions, [Zn2(1,4-CHDC)(1,10-phen)4]·(H2O)2(NO3)2 (I), [Zn(1,4-CHDC)] (II), [Zn3(1,3-CHDC)3(4,4'-bipy)] (III), [Zn5(OH)2(1,3-CHDC)4] (IV), and [Zn(1,2-CHDC)] (V), were prepared and characterised. Compound I is a molecular structure while II, III and V have two-dimensional layered structures. Compounds II, III and V are coordination polymers (I0O2) possessing zero-dimensional inorganic connectivity (In, n=0) and two-dimensional organic connectivity (Om, m=2). Compound IV is a coordination polymer (I0O3) possessing zero-dimensional inorganic connectivity (In, n=0) and three-dimensional organic connectivity (Om, m=3). In all these compounds, the CHDC anions are in the (e,e) conformation except in II, where it has the (a,e) conformation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cyclohexanedicarboxylates; Hybrid Compounds; Zinc Cyclohexanedicarboxylates; Carboxylate Ligands; Hydrothermal Synthesis; Structure Elucidation |
| ID Code: | 39981 |
| Deposited On: | 20 May 2011 12:30 |
| Last Modified: | 20 May 2011 12:30 |
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