Basavaiah, Deevi ; Muthukumaran, Kannan ; Sreenivasulu, Bandaru (2000) TMSOTf-catalyzed stereoselective isomerization of acetates of the Baylis-Hillman adducts Synthesis, 2000 (4). pp. 545-548. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2000-6372
Abstract
TMSOTf-catalyzed isomerization of acetates of the Baylis - Hillman adducts, i.e. methyl 3-acetoxy-3-aryl-2-methylenepropanoates and 3-acetoxy-3-aryl-2-methylenepropanenitriles providing methyl (2E)-2-(acetoxymethyl)-3-arylprop-2-enoates and (2E)-2-(acetoxymethyl)-3-arylprop-2-enenitriles, respectively, is described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | Baylis-Hillman Reaction; Trimethylsilyl Trifluoromethanesulfonate; Isomerization; Stereoselectivity; 1,2-interaction |
| ID Code: | 3931 |
| Deposited On: | 18 Oct 2010 09:24 |
| Last Modified: | 18 Oct 2010 09:24 |
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