Rao, Balachandra ; Mathur, H. B. (1971) Thermodynamics of the interaction of transition metal ions with histamine Journal of Inorganic and Nuclear Chemistry, 33 (3). pp. 809-816. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(71)80481-5
Abstract
The thermodynamic functions of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with histamine have been determined in a medium of 0·2M KNO3. The analysis of results shows the bis-histamino Cu(II) complex to be square planar, bis-histamino Co(II) and Ni(II) as octahedral and bis-histamino Zn(II) to have tetrahedral symmetry. A comparison of the thermodynamic functions of these complexes with the corresponding bis-histidino complexes indicates little electrostatic interaction in solution between carboxylic radical in histidine and these metal ions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 31390 |
| Deposited On: | 05 Mar 2011 05:36 |
| Last Modified: | 09 Jun 2011 08:17 |
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