Nag, Purnima ; Bohra, Rakesh ; Mehrotra, Ram C. ; Ratnani, Raju (2002) Chemistry of oxomolybdenum(V) and (VI) complexes incorporating oxygen, nitrogen, and/or sulfur donor atoms. II. Synthesis and characterization of some heteroleptic dioxomolybdenum(VI) complexes of the type [MoO2CL(L)l'] (L=dithiocarbamates or xanthates and L'=OPPh3 and DMSO) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 32 (9). pp. 1549-1559. ISSN 1553-3174
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Related URL: http://dx.doi.org/10.1081/SIM-120015079
Abstract
Heteroleptic dioxomolybdenum(VI) complexes of the type [MoO2Cl(L)L'] (L=diethyl dithiocarbamate, diisopropyl dithiocarbamate, pyrrolidine dithiocarbamate, piperidine dithio-carbamate, methyl xanthate or isopropyl xanthate; L'=triphenylphosphine oxide OPPh3 or dimethyl sulfoxide DMSO) have been synthesised by treating equimolar amounts of MoO2Cl2(L')2 with the sodium or potassium salts of the corresponding dithiocarbamates or xanthates. All of these derivatives are coloured solids which are soluble in polar solvents. They have been characterized by elemental analyses and spectral (electronic, IR, NMR) studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30280 |
| Deposited On: | 22 Dec 2010 10:27 |
| Last Modified: | 07 Jun 2011 04:31 |
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