Sharma, Suman ; Bohra, Rakesh ; Mehrotra, Ram C. (1996) Crystal and molecular structure of a novel mixed ligand complex of tin(IV),[(Et2NCS2)2Sn(O-C(CH3)= C(S)-C(O)-CH3)] Polyhedron, 15 (9). pp. 1525-1529. ISSN 0277-5387
Full text not available from this repository.
Official URL: http://dx.doi.org//10.1016/0277-5387(95)00391-6
Related URL: http://dx.doi.org/10.1016/0277-5387(95)00391-6
Abstract
Recrystallization of [BrSn(S2CNEt2)2(OC(CH3)CHCOCH3)] 1, formed from the reaction of Br2Sn(S2CNEt2)2 with Na(CH3COCHCOCH3) in 1:1 molar ratio yields [(Et2NCS2)2Sn(O-C(CH3)=C(S)-C(O)-CH3)] 2, a unique derivative, which was characterized by X-ray crystallography. The geometry around tin(IV) is distorted octahedral, with the average Sn---S distance [2.548(4)Å] of the chelated dithiocarbamate being longer than the Sn---S distance [2.388(5)Å] of the five-membered chelating > Sn(O-C(CH3)=C(S)-C(O)-CH3) ligand moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30086 |
| Deposited On: | 23 Dec 2010 03:16 |
| Last Modified: | 07 Jun 2011 04:39 |
Repository Staff Only: item control page
