Mehta, Goverdhan ; Khan, Faiz Ahmed ; Ganguly, Bishwajit ; Chandrasekhar, Jayaraman (1992) Importance of orbital and electrostatic interactions in determining π-facial selectivities in nucleophilic additions to endo-substituted bicyclo[2.2.2]octan-2-ones Journal of the Chemical Society, Chemical Communications . pp. 1711-1712. ISSN 0022-4936
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Official URL: http://www.rsc.org/publishing/journals/article.asp...
Related URL: http://dx.doi.org/10.1039/C39920001711
Abstract
The diastereoselectivities in nucleophilic additions to bicyclo[2.2.2]octan-2-ones can be modulated by distal endo-substituents; both orbital and electrostatic interactions contribute to the observed stereoselectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 29292 |
| Deposited On: | 17 Dec 2010 08:16 |
| Last Modified: | 16 Jul 2012 07:54 |
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