Mehta, Goverdhan ; Sen, Saikat (2009) Towards a temperature-guided molecular switch: an unusual reversible low-temperature polymorphic phase transition in a conformationally locked environment Chemical Communications (40). pp. 5981-5983. ISSN 1359-7345
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2009...
Related URL: http://dx.doi.org/10.1039/B905651C
Abstract
A conformationally locked tetraacetate undergoes, quite akin to a temperature-guided molecular switch, a reversible thermal switching between two polymorphic modifications; the room-temperature α- form converted at -4°C to a low-temperature denser β- form, which displayed an unusual kinetic stability till 67°C and transformed back to the a-form beyond this temperature.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 29226 |
| Deposited On: | 17 Dec 2010 08:22 |
| Last Modified: | 01 Mar 2011 08:23 |
Repository Staff Only: item control page
