Additive induced polymorphous behavior of a conformationally locked hexol

Mehta, Goverdhan ; Sen, Saikat ; Venkatesan, Kailasam (2007) Additive induced polymorphous behavior of a conformationally locked hexol CrystEngComm, 9 . pp. 144-151. ISSN 1466-8033

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2007...

Related URL: http://dx.doi.org/10.1039/B613949C

Abstract

The influence of molecular additives on the crystal structure adopted by a C2h symmetric, conformationally locked hexol 2 forms the object of the present study. It has been observed that the polycyclitol 2 crystallizes in two polymorphic (α and β forms) and one pseudopolymorphic (monohydrate) modification, depending on the presence and nature of the additive employed. Thus, with the sole exception of trimesic acid, which induces 2 to crystallize in the denser β form, the molecular additives screened in this study either failed to promote polymorphism in 2 or caused it to crystallize as a monohydrate. The putative role of trimesic acid in providing an alternate crystallization pathway to the polyol 2 has been discussed.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:28992
Deposited On:18 Dec 2010 05:43
Last Modified:17 May 2016 11:59

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