Yadav, Jhillu S. ; Gopalarao, Yerragorla ; Chandrakanth, Dandekar ; Reddy, Basi V. Subba (2016) Stereoselective Synthesis of the C(1) - C(28) Fragment of Amphidinol 3 Helvetica Chimica Acta, 99 (6). pp. 436-446. ISSN 0018-019X
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Official URL: http://doi.org/10.1002/Hlca.201500281
Related URL: http://dx.doi.org/10.1002/Hlca.201500281
Abstract
A stereoselective synthesis of the polyol side chain (C(1) – C(28)) of amphidinol 3 has been accomplished following Sharpless epoxidation, Crimmins aldol reaction, Jacobsen kinetic resolution, Sharpless asymmetric dihydroxylation, and our own reaction for the synthesis of a chiral allylic alcohol from an epoxy alcohol. The olefin functionality was introduced by a cross metathesis and Julia–Kocienski olefination.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 135705 |
| Deposited On: | 10 Aug 2023 10:15 |
| Last Modified: | 10 Aug 2023 10:15 |
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