Kumar, Avulu Vinod ; Rohullah, Mehdi ; Ravi, Jada ; Godumala, Mallesham ; Annadhasan, Mari ; Chandrasekar, Rajadurai (2021) Mechanophotonic aspects of a room temperature phosphorescent flexible organic microcrystal CrystEngComm, 23 (34). pp. 5774-5779. ISSN 1466-8033
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Official URL: http://doi.org/10.1039/D1CE00475A
Related URL: http://dx.doi.org/10.1039/D1CE00475A
Abstract
A combination of flexibility and room temperature phosphorescence (RTPR) in organic crystals is in high demand due to various applications from bio-medical to organic photonic circuit technologies. However, flexible RTPR crystals are scarce. We report the design and synthesis of novel flexible microcrystals of (Z)-3-(4-(10H-phenothiazin-10-yl)phenyl)-2-(3,5-bis(trifluoromethyl)phenyl)acrylonitrile (PTX-2CF3), exhibiting a phosphorescence lifetime of 658 μs and λmax ≈ 530 nm. The structural basis for the mechanical flexibility and mechanophotonic aspects of the PTX-2CF3 crystals is studied in detail.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry |
| ID Code: | 132538 |
| Deposited On: | 19 Dec 2022 09:43 |
| Last Modified: | 19 Dec 2022 09:43 |
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