Brahma, Sanfaori ; Asif Ikbal, Sk. ; Dey, Soumyajit ; Rath, Sankar Prasad (2012) Induction of supramolecular chirality in di-zinc(ii) bisporphyrin via tweezer formation: synthesis, structure and rationalization of chirality Chemical Communications, 48 (34). p. 4070. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/C2CC30526G
Related URL: http://dx.doi.org/10.1039/C2CC30526G
Abstract
Two new supramolecular complexes consisting of an achiral bisporphyrin host and a chiral diamine guest are reported. One shows a remarkably high amplitude bisignate CD signal while the other one shows a very low value. X-ray structure and other spectroscopic investigations of the tweezer complexes clearly rationalize the origin of the optical activity that has so far remained an unresolved issue.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 120911 |
| Deposited On: | 07 Jul 2021 06:15 |
| Last Modified: | 07 Jul 2021 06:15 |
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