Dioximes as Synthons for Medium Ring Heterocyclic Compounds

Singh, Maya Shankar ; Singh, Ashwani Kumar (2000) Dioximes as Synthons for Medium Ring Heterocyclic Compounds Heterocycles, 53 (4). p. 851. ISSN 0385-5414

Full text not available from this repository.

Official URL: http://doi.org/10.3987/COM-99-8825

Related URL: http://dx.doi.org/10.3987/COM-99-8825

Abstract

A simple and convenient synthetic approach to eight-, nine- and ten-membered nitrogen and oxygen containing heterocycles has been developed. 3,4-Diaryl-1,6,2,5-dioxadiazocines, (3) and (4), 3,4-diaryl-1,6,2,5-dioxadiazonines,(5) and 3,4-diaryl-1,6,2,5-dioxadiazacyclodeca-2,4-dienes (6) are prepared in one-pot from vicinal dioximes (1) via dianion intermediate (2) and 1,2-dibromoethylene, l,2-dichloroethane, 1,3-dibromopropane and 1,4-dichlorobutane, respectively. A plausible mechanism has bcen discussed.

Item Type:Article
Source:Copyright of this article belongs to Japan Institute of Heterocyclic Chemistry.
ID Code:120314
Deposited On:25 Jun 2021 10:43
Last Modified:25 Jun 2021 10:43

Repository Staff Only: item control page