Singh, M.S. ; Singh, Pratibha ; Singh, Pallavi (2008) ChemInform Abstract: New Tandem Reactions for the Construction of Heterocycles via Dianion Strategy. ChemInform, 39 (36). p. 767. ISSN 0931-7597
Full text not available from this repository.
Official URL: https://doi.org/10.1002/chin.200836182
Related URL: http://dx.doi.org/10.1002/chin.200836182
Abstract
The reaction of chiral and achiral salen ditopic ligands with sodium in dry isopropanol generates remote O,O-dianions. The dianions thus generated in situ are trapped by suitable phosphorus dielectrophiles to yield 2-oxo and 2-thioxo-1,3,7-dioxazaphosphadecines and 2-oxo and 2-thioxo-1,3,7,10-dioxadiazaphosphatridecines in moderate to good overall yield. The products are characterized by elemental and spectral (IR, 1 H, 13 C, 31 P NMR and Mass) studies. A plausible mechanistic logic and concept utilized in the synthesis have been discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 120265 |
| Deposited On: | 24 Jun 2021 12:13 |
| Last Modified: | 24 Jun 2021 12:13 |
Repository Staff Only: item control page
