An oxalato-bridged copper(II) complex

Cheng, Jack ; Liao, Fen-Ling ; Lu, Tian-Huey ; Mukherjee, Partha S. ; Maji, Tapas K. ; Chaudhuri, N. Ray (2001) An oxalato-bridged copper(II) complex Acta Crystallographica Section E, 57 (7). m263-m264. ISSN 1600-5368

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Official URL: http://doi.org/10.1107/S1600536801007814

Related URL: http://dx.doi.org/10.1107/S1600536801007814

Abstract

In the coordination complex μ-oxalato-bis­[(iso­cyanato-N)(tetra­methyl­ethyl­enedi­amine)copper(II)], [Cu2(NCO)2(C2O4)(C6H16N2)2], the CuII ions are five-coordinated. One CuII ion bridges to another centrosymmetry-related CuII ion through C2O42−, forming a plane with an r.m.s. deviation of 0.059 Å. The O—Cu—O angle is 79.33 (8)° and the Cu⋯Cu separation is 5.14 Å.

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