Mukherjee, Partha Sarathi ; Min, Kil Sik ; Arif, Atta M. ; Stang, Peter J. (2004) Synthesis and Crystal Structure of Two New Discrete, Neutral Complexes of Manganese and Zinc Using a Rigid Organic Clip Inorganic Chemistry, 43 (20). pp. 6345-6350. ISSN 0020-1669
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Official URL: http://doi.org/10.1021/ic0493088
Related URL: http://dx.doi.org/10.1021/ic0493088
Abstract
Two discrete neutral dimanganese(II) and tetrazinc(II) complexes were synthesized from a rigid organic clip and the corresponding metal acetates. The compounds were characterized by elemental analysis and single crystal X-ray diffraction study. The manganese species is a dinuclear discrete product with two disordered acetates bridging two manganese centers, while the zinc one consists of two octahedral and two tetrahedral Zn(II) centers with both bridging acetates and triply μ3-hydroxides. Variable temperature magnetic measurement reveals the existence of weak antiferromagnetic interaction (J = −1.6 cm-1; H = −2JS1·S2) within the manganese complex.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 119418 |
| Deposited On: | 12 Jun 2021 17:55 |
| Last Modified: | 12 Jun 2021 17:55 |
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