Venkataramudu, Uppari ; Chandrasekhar, Naisa ; Basak, Supratim ; Prasad, Muvva D. ; Chandrasekar, Rajadurai (2015) Fabrication of High-Resolution 4,82 -Type Archimedean Nanolattices Composed of Solution Processable Spin Cross-Over Fe(II) Metallosupramolecular Polymers Macromolecular Rapid Communications, 36 (7). pp. 647-653. ISSN 1022-1336
Full text not available from this repository.
Official URL: http://doi.org/10.1002/marc.201400628
Related URL: http://dx.doi.org/10.1002/marc.201400628
Abstract
This paper presents the synthesis of two highly soluble Fe(II) metallosupramolecular polymers with two counter anions from a novel back‐to‐back coupled hybrid ligand. The spin cross‐over (SCO) temperature of polymers with BF4 and ClO4 counter anions is T1/2 = 313 K and T1/2 = 326 K, respectively. By following the top‐down approach, one of the polymers (with ClO4 counter anion) is successfully solution processed using a lithographically controlled wetting technique to create laser readable high‐resolution Archimedean (4,82) nanolattices (consist of diamagnetic octagons and SCO squares). The thickness and top area of each SCO square are ≈75 nm and ≈2 × 2 μm2, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Coordination Polymers; Fe(Ii) Ions; Lithography; Nanopatterns; Spin Cross‐over Effects. |
| ID Code: | 117405 |
| Deposited On: | 23 Apr 2021 06:10 |
| Last Modified: | 23 Apr 2021 06:10 |
Repository Staff Only: item control page
