Solid-state architecture of saccharin salts of some diamines

Banerjee, Rahul ; Saha, Binoy K. ; Desiraju, Gautam R. (2006) Solid-state architecture of saccharin salts of some diamines Acta Crystallographica Section C, 62 (6). o346-o349. ISSN 0108-2701

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Official URL: http://doi.org/10.1107/S0108270106016374

Related URL: http://dx.doi.org/10.1107/S0108270106016374

Abstract

Hydrazinium saccharinate, N2H5+·C7H4NO3S-, crystallizes in a 1:1 ratio, while ethyl­ene­diaminium bis­(saccharinate), C2H10N22+·2C7H4NO3S-, and butane-1,4-diaminium bis­(sac­charin­ate), C4H14N22+·2C7H4NO3S-, form in a 1:2 cation-anion stoichiometry. The structures contain many strong hydrogen bonds of the N+-H...N-, N+-H...O, N-H...O and N-H...N types, with auxiliary C-H...O inter­actions.

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