Maji, Tapas Kumar ; Laskar, Inamur Rahaman ; Mostafa, Golam ; Welch, Alan J. ; Mukherjee, Partha Sarathi ; Chaudhuri, Nirmalendu Ray (2001) A 1D thiocyanato bridge nickel(II) system: crystal structure and magnetic property Polyhedron, 20 (7-8). pp. 651-655. ISSN 0277-5387
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Official URL: https://www.sciencedirect.com/science/article/pii/...
Related URL: http://dx.doi.org/10.1016/S0277-5387(01)00729-X
Abstract
A one-dimensional coordination polymer of nickel(II), [(μN,S-NCS)2{Ni(ampy)}]n (ampy=1-(2-aminoethyl)pyrrolidine) has been synthesized and characterized by X-ray single crystal analysis. Structure analysis reveals that each nickel(II) center is coordinated in a distorted octahedral fashion with four bridging thiocyanato ligands and one mesocyclic diamine ligand. The low temperature (300–18 K) magnetic measurement shows that the system is ferromagnetically coupled. The magnetic data are fitted to the de Neef equation, giving the parameters J=1.4 cm-1 and g=2.08.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Crystal Structures; Magnetic Properties; Nickel(II) Complexes; Thiocyanato Bridge Complexes; 1D Polymer |
| ID Code: | 114764 |
| Deposited On: | 30 May 2018 10:18 |
| Last Modified: | 30 May 2018 10:18 |
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