Honeycomb porous framework of Zinc (II): effective host for palladium nanoparticles for efficient three-component (A3) coupling and selective gas storage

Jayaramulu, Kolleboyina ; Datta, Kasibhatta K. R. ; Suresh, Mothika V. ; Kumari, Gayatri ; Datta, Ranjan ; Narayana, Chandrabhas ; Eswaramoorthy, Muthusamy ; Maji, Tapas Kumar (2012) Honeycomb porous framework of Zinc (II): effective host for palladium nanoparticles for efficient three-component (A3) coupling and selective gas storage ChemPlusChem, 77 (9). pp. 743-747. ISSN 2192-6506

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Official URL: https://onlinelibrary.wiley.com/doi/full/10.1002/c...

Related URL: http://dx.doi.org/10.1002/cplu.201200093

Abstract

MOF for effective stabilizer for “Pd” and selective host for CO2: A porous, layered MOF system {[Zn(Himdc)(bipy)].DMF} (1; Himdc = 4,5‐imidazoledicarboxylate, bipy = 4,4'‐bipyridine) shows selective gas‐storage properties, while the polar nanochannels serve as functional scaffold for the stabilization of highly dispersed Pd nanoparticles. The Pd@MOF1 a hybrid is a highly active and recyclable catalyst for the synthesis of propargylamine derivatives through A3 coupling reactions.

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Deposited On:23 Apr 2018 11:27
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