Propargyl/methyl furanosides as potential glycosyl donors

Vidadala, Srinivasa Rao ; Gayatri, Gaddamannugu ; Sastry, G. Narahari ; Hotha, Srinivas (2011) Propargyl/methyl furanosides as potential glycosyl donors Chemical Communications, 47 (35). pp. 9906-9908. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...

Related URL: http://dx.doi.org/10.1039/C1CC13134F

Abstract

Transfuranosylations are not well studied though many similar studies exist for transpyranosylation; herein, we report that propargyl/methyl D-ribf- and D-lyxf- give only 1,2-transglycosides whereas D-araf- and D-xylf- result in a mixture of 1,2-trans and 1,2-cisglycosides; observed facts are rationalised by computational studies.

Item Type:Article
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ID Code:108107
Deposited On:28 Jul 2017 05:46
Last Modified:28 Jul 2017 05:46

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