“On Water” C(sp3)–H functionalization/C–O/C–N bonds formations: synthesis of functionalized oxazolidines and imidazolidines

Satheesh, Vanaparthi ; Sengoden, Mani ; Punniyamurthy, Tharmalingam (2016) “On Water” C(sp3)–H functionalization/C–O/C–N bonds formations: synthesis of functionalized oxazolidines and imidazolidines The Journal of Organic Chemistry, 81 (20). pp. 9792-9801. ISSN 0022-3263

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b0185...

Related URL: http://dx.doi.org/10.1021/acs.joc.6b01850

Abstract

On water oxidative C(sp3)–H functionalization/C–O/C–N bonds formations using tetrabutylammonium iodide as the catalyst and tert-butyl hydroperoxide in water (T-Hydro) as the oxidant affords a potential route for the construction of functionalized oxazolidines and imidazolidines. The reaction is simple, regioselective, and effective at moderate temperature with broad substrate scope. In the case of optically active substrates, the oxidative cyclization can be accomplished with high optical purities.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:106966
Deposited On:22 Jun 2017 09:58
Last Modified:22 Jun 2017 09:58

Repository Staff Only: item control page