Narute, Sachin B. ; Kiran, Neella Chandra ; Ramana, Chepuri V. (2011) A [Pd]-mediated ω-alkynone cycloisomerization approach for the central tetrahydropyran unit and the synthesis of C(31)–C(48) fragment of aflastatin A Organic & Biomolecular Chemistry, 9 (15). pp. 5469-5475. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2011...
Related URL: http://dx.doi.org/10.1039/C1OB05251A
Abstract
A concise assembly of the central tetrahydropyran unit of aflastatin A featuring a Pd-mediated alkynone cycloisomerization to provide a glycal and its subsequent stereoselective hydroboration to deliver the requisite stereochemistry at C(33) and C(34) centers is documented.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 106011 |
| Deposited On: | 01 Feb 2018 16:54 |
| Last Modified: | 01 Feb 2018 16:54 |
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