Short step enantioselective synthesis of (−)-swainsonine

Punniyamurthy, T. ; Irie, Ryo ; Katsuki, Tsutomu (2000) Short step enantioselective synthesis of (−)-swainsonine Chirality, 12 (5-6). pp. 464-468. ISSN 0899-0042

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/(SICI)1...

Related URL: http://dx.doi.org/10.1002/(SICI)1520-636X(2000)12:5/6<464::AID-CHIR28>3.0.CO;2-Z

Abstract

Recent discovery of asymmetric desymmetrization of meso-heterocycles using (R,R)-(salen)manganese complex 2 as a catalyst allowed easy access to optically active 2,3,4-trisubstituted pyrrolidines. Taking advantage of this new reaction, we could achieve the short-step synthesis of (−)-swainsonine 1.

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