Choudhary, V. R. ; Rajput, A. M. ; Prabhakar, B. (1992) Low temperature oxidative conversion of methane to syngas over NiO-CaO catalyst Catalysis Letters, 15 (4). pp. 363-370. ISSN 1011-372X
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Official URL: http://www.springerlink.com/content/q245173nh11317...
Related URL: http://dx.doi.org/10.1007/BF00769159
Abstract
Catalytic partial oxidation of methane over NiO-CaO (with or without its prereduction by H2) at low temperatures ( ≤ 973 K) under non-equilibrium conditions yields syngas (H2/CO ratio ≈ 2.0) with high conversion/selectivity and extremely high productivity. If required, the H2/CO ratio can be increased by adding water vapour to the feed. Product selectivity is controlled by the process kinetics and also the reaction path is different from that observed for the high-temperature non-catalytic and catalytic processes operating at equilibrium.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Methane Conversion; Synthesis Gas; Nickel-calcium Oxide |
| ID Code: | 10351 |
| Deposited On: | 04 Nov 2010 05:57 |
| Last Modified: | 30 May 2011 04:44 |
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