Zgierski, Marek Z. ; Chakraborty, Tapas ; Lim, E. C. (1993) Inter-ring exchange interactions in the excited electronic state of bridged diaryl compounds: exciton splitting in 9,10-dihydroanthracene and dibenzosuberane The Journal of Chemical Physics, 98 (12). Article ID 9340. ISSN 0021-9606
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Official URL: http://scitation.aip.org/content/aip/journal/jcp/9...
Related URL: http://dx.doi.org/10.1063/1.464413
Abstract
The fluorescence excitation spectra of jet‐cooled 9,10‐dihydroanthracene and dibenzosuberane, in the region of their lowest‐energy absorption band, exhibit two close‐lying electronic origins that can be identified as the two exciton components of the lowest‐energy benzene transition. The measured band positions and intensities of the two exciton components are in good agreement with the results of CNDO/S+CIS calculations based on the optimized QCFF/PI+CIS ground‐state geometry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| ID Code: | 100601 |
| Deposited On: | 06 Dec 2016 11:55 |
| Last Modified: | 06 Dec 2016 11:55 |
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