Conformational studies of xanthene by laser-induced fluorescence in a supersonic free jet: inversion potentials in ground and excited singlet states

Chakraborty, Tapas ; Lim, Edward C. (1993) Conformational studies of xanthene by laser-induced fluorescence in a supersonic free jet: inversion potentials in ground and excited singlet states The Journal of Chemical Physics, 98 (2). Article ID 836. ISSN 0021-9606

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Official URL: http://scitation.aip.org/content/aip/journal/jcp/9...

Related URL: http://dx.doi.org/10.1063/1.464247

Abstract

The analyses of fluorescence excitation and dispersed fluorescence spectra of jet‐cooled xanthene indicate that the equilibrium conformation of the molecule is nonplanar in the ground state and planar in the lowest excited singlet state. The estimated ground‐state inversion barrier is 50 cm-1.

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ID Code:100600
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